According to the law of conservation of energy, what will most likely happen in a closed system

The conservation of energy is an absolute law, and yet it seems to fly in the face of things we observe every day. Sparks create a fire, which generates heat—manifest energy that wasn’t there before. A battery produces power. A nuclear bomb creates an explosion. Each of these situations, however, is simply a case of energy changing form. Even the seemingly paradoxical dark energy causing the universe’s expansion to accelerate, we will see, obeys this rule.  

The law of conservation of energy, also known as the first law of thermodynamics, states that the energy of a closed system must remain constant—it can neither increase nor decrease without interference from outside. The universe itself is a closed system, so the total amount of energy in existence has always been the same. The forms that energy takes, however, are constantly changing.

 

Potential and kinetic energy are two of the most basic forms, familiar from high school physics class: Gravitational potential is the stored energy of a boulder pushed up a hill, poised to roll down. Kinetic energy is the energy of its motion when it starts rolling. The sum of these is called mechanical energy. The heat in a hot object is the mechanical energy of its atoms and molecules in motion. In the 19th century physicists realized that the heat produced by a moving machine was the machine’s gross mechanical energy converted into the microscopic mechanical energy of atoms. Chemical energy is another form of potential energy stored in molecular chemical bonds. It is this energy, stockpiled in your bodily cells, that allows you to run and jump. Other forms of energy include electromagnetic energy, or light, and nuclear energy—the potential energy of the nuclear forces in atoms. There are many more. Even mass is a form of energy, as Albert Einstein’s famous E = mc2 showed.

  Fire is a conversion of chemical energy into thermal and electromagnetic energy via a chemical reaction that combines the molecules in fuel (wood, say) with oxygen from the air to create water and carbon dioxide. It releases energy in the form of heat and light. A battery converts chemical energy into electrical energy. A nuclear bomb converts nuclear energy into thermal, electromagnetic and kinetic energy.  

As scientists have better understood the forms of energy, they have revealed new ways for energy to convert from one form to another. When physicists first formulated quantum theory they realized that an electron in an atom can jump from one energy level to another, giving off or absorbing light. In 1924 Niels Bohr, Hans Kramers, and John Slater proposed that these quantum jumps temporarily violated energy conservation. According to the physicists, each quantum jump would liberate or absorb energy, and only on average would energy be conserved.

  Einstein objected fervently to the idea that quantum mechanics defied energy conservation. And it turns out he was right. After physicists refined quantum mechanics a few years later, scientists understood that although the energy of each electron might fluctuate in a probabilistic haze, the total energy of the electron and its radiation remained constant at every moment of the process. Energy was conserved.  

Modern cosmology has offered up new riddles in energy conservation. We now know that the universe is expanding at a faster and faster rate—propelled by something scientists call dark energy. This is thought to be the intrinsic energy per cubic centimeter of empty space. But if the universe is a closed system with a finite amount of energy, how can it spawn more empty space, which must contain more intrinsic energy, without creating additional energy?

  It turns out that in Einstein’s theory of general relativity, regions of space with positive energy actually push space outward. As space expands, it releases stored up gravitational potential energy, which converts into the intrinsic energy that fills the newly created volume. So even the expansion of the universe is controlled by the law of energy conservation.

According to the law of conservation of energy, what will most likely happen in a closed system

by Chris Woodford. Last updated: March 21, 2021.

Gobble down five bananas and you'll have enough energy to swim for about an hour. That's because your body is a complex machine capable of turning one kind of energy (food) into another kind (movement). Cars can pull off the same trick. Depending on which make and model you own, you probably know that it does so many kilometers or miles to the gallon; in other words, using a certain amount of energy-rich gasoline, it can transport you (and a moderate load) a certain distance down the road. What we have here are two examples of machines—the human body and the automobile—that obey one of the most important laws of physics: the conservation of energy. Written in its simplest form, it says that you can't create or destroy energy, but you can convert it from one form into another. Pretty much everything that happens in the universe obeys this fundamental law. But why, and what use is it anyway? Let's take a closer look!

Photo: The conservation of energy: Walk upstairs and you have more potential energy when you get to the top than you had at the bottom—but you haven't created energy out of thin air. The muscles in your body have to work against the force of gravity to move you upwards and your body loses energy (that it made from food) as it climbs. This is the energy that your body regains as potential energy.

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The first thing we need to note is that the law of conservation of energy is completely different from energy conservation. Energy conservation means saving energy through such things as insulating your home or using public transportation; generally it saves you money and helps the planet. The conservation of energy has nothing to do with saving energy: it's all about where energy comes from and where it goes.

Write the law formally and it sounds like this:

In a closed system, the amount of energy is fixed. You can't create any more energy inside the system or destroy any of the energy that's already in there. But you can convert the energy you have from one form to another (and sometimes back again).

A "closed system" is a bit like a sealed box around whatever we're studying: no energy can leak into the box from the inside (or be introduced to the box from outside).

There are some even simpler, more familiar ways of stating the conservation of energy. "No pain, no gain" is a rough everyday equivalent: if you want something, you have to work for it. "There's no such thing as a free lunch" and "You don't get anything for free" are other examples.

According to the law of conservation of energy, what will most likely happen in a closed system

Artwork: This house is an example of a closed system: the energy that's inside the red dotted line stays as it is or gets converted into other forms. We can't create any new energy inside the house out of nothing at all, and we can't make energy inside the house vanish without trace, though we can turn it into other forms. So what if one room of the house suddenly starts getting hotter? The heat energy making that happen must be coming from energy that's already inside the house in a different form (maybe it's wood in a fire that's being burned to release the chemical energy locked inside it). If that's not the case, we don't have a closed system: the "extra" heat must be coming into the house from outside (maybe strong sunlight streaming in through the window).

The conservation of energy (and the idea of a "closed system") sounds a bit abstract, but it becomes an awful lot clearer when we consider some real-life examples.

Driving a car

Fill a car up with gasoline and you have a closed system. All the energy you have at your disposal is locked inside the gas in your tank in chemical form. When the gas flows into your engine, it burns with oxygen in the air. The chemical energy in the gas is converted first into heat energy: the burning fuel makes hot expanding gas, which pushes the pistons in the engine cylinders. In this way, the heat is converted into mechanical energy. The pistons turn the crankshaft, gears, and driveshaft and—eventually—the car's wheels. As the wheels turn, they speed the vehicle along the road, giving it kinetic energy (energy of movement).

If a car were 100 percent efficient, all the chemical energy originally locked inside the gasoline would be converted into kinetic energy. Unfortunately, energy is wasted at each stage of this process. Some is lost to friction when metal parts rub and wear against one another and heat up; some energy is lost as sound (cars can be quite noisy—and sound is energy that has to come from somewhere) Not all the energy the car produces moves you down the road: quite a lot has to push against the air (so it's lost to air resistance or drag), while some will be used to power things like the headlights, air conditioning, and so on. Nevertheless, if you measure the energy you start with (in the gasoline) and calculate how much energy you finish with and lose on the way (everything from useful kinetic energy and useless energy lost to friction, sound, air resistance, and so on), you'll find the energy account always balances: the energy you start with is the energy you finish with.

According to the law of conservation of energy, what will most likely happen in a closed system

Artwork: Like everything else, cars must obey the law of conservation of energy. They convert the energy in fuel into mechanical energy that moves you down the road, but waste quite a lot of energy in the process. If you put 100 units of energy into a car (in the form of fuel), only 15 units or so move you down the road. The rest is wasted as heat losses in the engine (74 percent); parasitic losses (6%, making electricity, for example, to light the headlamps); and drivetrain losses (5%, sending power to the wheels). The 15 useful units of energy are used to overcome drag (air resistance), friction (in the brakes), and rolling resistance (in the tires). Every bit of energy we put into a car has to go somewhere, so the energy outputs (74% + 6% + 5% + 15%) must always exactly add up to the original energy input (100%). Figures for city driving from Where the energy goes, fueleconomy.gov.

Now this only applies if your car is a "closed system." If you're driving along the straight and the road suddenly starts going downhill, you're going to be able to go much further than you'd be able to go otherwise. Does this violate the conservation of energy? No, because we're no longer dealing with a closed system. Your car is gaining kinetic energy from the gasoline in its tank, but it's also gaining kinetic energy because it's going downhill. This isn't a closed system so the conservation of energy doesn't apply anymore.

Boiling a kettle

According to the law of conservation of energy, what will most likely happen in a closed system

Photo: An electric kettle like this converts electrical energy into heat energy. That's the reverse of the process that happens in the power plant that supplies your home, where electricity is produced using heat energy released by burning a fuel such as coal, oil, or gas.

Boil water with an electric kettle and you're seeing the conservation of energy at work again. Electrical energy drawn from the power outlet on your wall flows into the heating element in the base of your kettle. As the current flows through the element, the element rapidly heats up, so the electrical energy is converted into heat energy that gets passed to the cold water surrounding it. After a couple of minutes, the water boils and (if the power stays on) starts to turn to steam. How does the conservation of energy apply here? Most of the electrical energy that enters the kettle is converted into heat energy in the water, though some is used to provide latent heat of evaporation (the heat we need to give to liquids to turn them into gases such as steam). If you add up the total electrical energy "lost" by the electricity supply and the total energy gained by the water, you should find they're almost exactly the same. Why aren't they exactly equal? Simply because we don't have a closed system here. Some of the original energy is converted to sound and wasted (kettles can be quite noisy). Kettles also give off some heat to their surroundings—so that's also wasted energy.

Pushing a car uphill

In the everyday world, "work" is something you do to earn money; in physics, work has a different meaning. When you do a useful job with a force (a push or a pull), such as moving a car uphill, we say you're doing work, and that takes energy. If you push a car uphill, it has more potential energy at the top of the hill than it had at the bottom. Have you violated the conservation of energy by creating potential energy out of thin air?

No! To push the car, you have to do work against the force of gravity. Your body has to use energy to do work. Most of the energy your body uses is gained by the car as you push it uphill. The energy your body loses is pretty much equal to the work it does against gravity. And the energy the car gains is the same as the work done. So no energy is created or destroyed here: you're simply converting energy stored as fuel inside your body into potential energy stored by the car (because of its height).

According to the law of conservation of energy, what will most likely happen in a closed system

Artwork: When you push a car uphill, the potential energy it gains comes from the energy your body loses in the process.

Who discovered the conservation of energy?

“... the quantity of heat produced by the friction of bodies, whether solid or liquid, is always proportional to the quantity of force expended.”

James Prescott Joule, The Mechanical Equivalent of Heat, 1845.

How do we know the conservation of energy is true? First, it sounds sensible. If you put a heavy log on a fire it might burn for an hour. If you put a second log, roughly the same size, on the fire, it's reasonable to suppose you'll get twice as much heat or the fire will burn twice as long. By the same token, if five bananas can supply your body with an hour's energy, ten bananas should keep you running for two hours—although you might not enjoy guzzling them all at once! In other words, the energy in (the logs you add to the fire or the bananas you eat) is equal to the energy out (the heat you get by burning logs or the energy you make by eating bananas).

Reasonable guesswork doesn't quite cut the mustard in science. Really, we need to be sure that the energy we start with in a closed system is the same as the energy we end up with. So how do we know this? One of the first people to confirm the law of conservation of energy experimentally was English physicist James Prescott Joule (1818–1889), who used an ingenious bit of apparatus to find what he called "the mechanical equivalent of heat." He used a falling weight to drive a large paddle wheel sealed inside a container of water. He calculated the potential energy of the weight (the energy it had because of its height above Earth) and reasoned that, as the weight fell, it transferred pretty much all its energy to kinetic energy in the paddle wheel. As the paddle wheel turned, it stirred the water in the container and warmed it up by a small but significant amount. Now we know how much energy it takes to warm a certain mass of water by a certain number of degrees, so Joule was able to figure out how much energy the water had gained. To his delight, he found out that this figure exactly matched the energy lost by the falling weight. Joule's brilliant work on energy was recognized when the international scientific unit of energy (the joule) was named for him.

According to the law of conservation of energy, what will most likely happen in a closed system

Photo: The Mechanical Equivalent of Heat: In James Prescott Joule's famous experiment, a falling weight (1) pulls on a rope that passes over a pulley (2). The rope spins an axle (3) that turns a paddle inside a sealed container of water (4). As the paddle spins, the water heats up. Joule proved that the heat energy gained by the water was exactly the same as the potential energy lost by the weight.

Joule built on earlier work by Anglo-American physicist Benjamin Thompson (1753–1814), also known as Count Rumford. While working in a Germany artillery factory, Rumford noted that cannon barrels got hot when they were being drilled out. He swiftly realized that the heat was not a magic property of the metal (as many people supposed) but came from the mechanical, frictional process of drilling: the more you drilled, the hotter the metal got. Rumford's simple calculations produced results that, according to Joule, were "not very widely different from that which I have deduced from my own experiments." That was a sign both men were on the right track.

Back in the 19th century, charlatan inventors would pop up from time to time showing off miracle machines that seemed to be able to drive themselves forever. Inventions like this are called perpetual motion machines: they seem to be able to move forever without anyone adding any more energy. Often, machines like this were blatant tricks: the mechanisms were powered by a concealed assistant who sat in the shadows turning a hidden handle! Some of the machines sound plausible, but all of them unfortunately fall foul of the conservation of energy.

According to the law of conservation of energy, what will most likely happen in a closed system

In one version of perpetual motion, illustrated here, water (1) tips down onto a waterwheel, turning it around (2). The turning wheel drives gears (3) that power an Archimedes screw, which lifts the water back up to the top, theoretically allowing the whole cycle to repeat itself forever. Although you might think energy is being recycled as the water moves around, it's also being lost all the time. The water at the top has potential energy and that can indeed drive a waterwheel as it falls. But some energy will be lost to friction as the wheel turns. More energy will be lost to friction in the gears and the screw. So, between them, the wheel, gears, and screw will not have the same amount of energy as the potential energy the water lost originally. That means the screw cannot lift as as much water back to the bath as fell down from it originally—so the machine will very quickly come to a stop.

Find out more

  • The Museum of Unworkable Devices: An excellent website about perpetual motion machines (and similar unworkable devices) compiled by Donald E. Simanek, former professor of physics at Lockhaven University.

Nuclear reactions seem to create energy out of nothing breaking up or joining together atoms. Do they violate the conservation of energy? No!

Albert Einstein's famous equation E=mc2 shows that energy and mass are different forms of the same thing. Loosely speaking, you can convert a small amount of mass into a large amount of energy (as in a nuclear power plant, where large atoms split apart and give off energy in the process). Einstein's equation shows us we sometimes need to factor mass into the conservation of energy. In a nuclear reaction, we start off with one set of atoms (a certain amount of energy in the form of mass) and end up with a different set of atoms (a different amount of energy locked in their mass) plus energy that's released as heat. If we factor in the mass of the atoms before and after the reaction, plus the energy released in the process, we find the conservation of energy is satisfied exactly. Since mass is a form of energy, it's clear that we can't destroy mass or create it out of nothing in the same way that we can't create or destroy energy. You'll sometimes see this referred to as the conservation of mass.

  • Atomic energy
  • Atoms
  • Energy
  • The Mechanical Equivalent of Heat: A good Wikipedia article about James Prescott Joule's famous experiment.
  • The Conservation of Energy: In this short video clip from his MIT lectures, Professor Walter Lewin demonstrates very impressively that you can't finish up with more energy than you started off with. Luckily for him, as it turns out!
  • Eyewitness Energy by Jack Challoner and Dan Green. Dorling Kindersley, 2016. A simple introduction to the science, technology, and history of energy. Ages 9–12.
  • Energy by Chris Woodford. Dorling Kindersley, 2007. My own colorful introduction explains what energy is, where it comes from, and how we use it in our everyday lives. Ages 9–12.
  • Power and Energy by Chris Woodford. Facts on File. This longer book of mine is a history of human efforts to harness energy, from ancient technologies like water power to the latest forms of renewable energy. Suitable for most readers from about ages 10 upward.
  • Great Experiments in Physics: Firsthand Accounts from Galileo to Einstein by Morris H. Shamos. Dover, 1959/1987. This utterly wonderful book (one of my favorite books ever!) contains reprints of papers reporting many of the greatest physics experiments of all time, including "Chapter 12. The Mechanical Equivalent of Heat" by James Prescott Joule. You may be able to read the whole paper via Google Books if you scroll through to page 166.
  • Six Easy Pieces by Richard Feynman. Basic Books, 2011. Chapter 4 is a clear, simple, theoretical explanation of the conservation of energy.

A few older articles from the archives explore the law in more depth:

  • The Discovery of the Law of Conservation of Energy by G. Sarton et al, Isis, Vol. 13, No. 1 (Sep., 1929). This article traces the history of the conservation of energy back through Mayer, Joule, Carnot, and others.
  • On the Principle of the Conservation of Energy by Ernst Mach, The Monist, Vol. 5, No. 1 (October, 1894), pp. 22–54 (33 pages). Mach discusses the broader signifance of the law and in terms of our concepts of energy.
  • Conservation of energy in the human bodyA>, Scientific American, Vol. 81, No. 6, August 5, 1899.